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Lecture 15: Electrochemistry

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FieldValue
SourceGeneral Lectures on Electrical Engineering
Year1908
Section IDgeneral-lectures-electrical-engineering-lecture-15
Locationlines 9343-9686
Statuscandidate
Word Count2071
Equation Candidates In Section10
Figure Candidates In Section0
Quote Candidates In Section0
FIFTEENTH LECTURE ELECTROCHEMISTRY LECTROCHEMISTRY is one of the most important applications of electric power, and possibly even more power is used for electrochemical work than for rail- roading. In electrochemical industries the most expensive part is electric power; material and labor are usually much less. Such industries therefore are located at water powers, where the cost of power is very low. The main classes of electrochemical work are : A. Electrol3rtic. B. Electrometallurgical. A. Ei^ECTROivYTic Work. . The chemical action of the current is used, by electrolyz- ing either solutions of salts or fused salts or compounds. Electrolysis of solutions in water is possible only with such metals which have less chemical affinity than hydrogen. For instance, Cu, Fe, and Zn can be deposited from salt solu- tions in water, but not Al, Mg, Na,
... es. Alternating current is used very little for electrolytic work, as with organic compounds to produce oxidation and reduction at the same time; that is, act on the compound in rapid succession by oxygen and hydrogen, the one during the one, the other during the next half wave of current. Very active metals like manganese and silicon dissolve by alternating current; that is, one-half wave dissolves, but the other does not deposit again. Very inert metals like platinum are deposited by alternat- ing current; that is, the negative half wave depos ...
... ower; material and labor are usually much less. Such industries therefore are located at water powers, where the cost of power is very low. The main classes of electrochemical work are : A. Electrol3rtic. B. Electrometallurgical. A. Ei^ECTROivYTic Work. . The chemical action of the current is used, by electrolyz- ing either solutions of salts or fused salts or compounds. Electrolysis of solutions in water is possible only with such metals which have less chemical affinity than hydrogen. For instance, Cu, Fe, and Zn can be deposited from salt ...
... that is, the negative half wave deposits by alter- nating current, but the positive half wave does not dissolve. ELECTROCHEMISTRY 203 B, ElvECTROMETAI,I,URGICAI. WORK. In electrometallurgical work the heat is used to produce the chemical action; thus it is immaterial whether alternating or direct current is used. The voltage required is still low but not as low as in elec- trolytic work : The carborundum furnace takes from 250 to 90, mostly about 100 volts; that is, it starts cold with 250 volts. While heating up the resistance drops, and th ...
Concept CandidateHits In SectionStatus
Ether1seeded
Term CandidateHits In SectionStatus
ether1seeded
Candidate IDOCR / PDF-Text CandidateSource Location
general-lectures-electrical-engineering-eq-candidate-0105containing water is 1.4 + the tr drop in the resistance of theline 9382
general-lectures-electrical-engineering-eq-candidate-01062CI + H2O = CIH + ClOH, that is, hydrochloric + hypo-line 9480
general-lectures-electrical-engineering-eq-candidate-01076C1 + 3H2O = 5CIH +C108H, that is hydrochloric andline 9488
general-lectures-electrical-engineering-eq-candidate-0108of carbides, CO therefore always forms and not CO2, sinceline 9587
general-lectures-electrical-engineering-eq-candidate-0109is, up to 35oo°C, when using carbon.line 9624
general-lectures-electrical-engineering-eq-candidate-0110CaO + 3C = CaC^ + CO.line 9636
general-lectures-electrical-engineering-eq-candidate-0111SiO^ -f 3C = SiC + 2CO.line 9650
general-lectures-electrical-engineering-eq-candidate-0112SiOa + 20 = Si + 2CO.line 9664
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